Free Online Hazmat/Hazchem Guide

Free Hazmat (Hazardous Materials)/HazChem (Hazardous Chemicals) Guide containing information on Supply Labels, Hazard Warning Panels, Hazard Warning Diamonds, Emergency Action Codes and more

 

GHS Labels

Hazard Warning Panel

Emergency Action Codes (EAC)

International Operations (ADR)

Blank Plates

Hazard Identification Number (HIN)

Hazard Warning Diamonds

Supply Labelling

  

NEW! Hazchem Scale Cards

Helping you manage chemical safety

With all the recent and pending legislation changes, NCEC have released a new Hazchem Scale Card. 

'More information on Hazchem Scalecards'.

This handy-sized reference guide gives you information on:

• NEW! GHS Labels
• Hazchem Warning Panels, Emergency Action Codes, ADR 2009
• New and updated Hazard Identification Numbers (HIN)
• Hazard Warning Diamonds and Supply Labelling

NOTE: We recieved feedback from our customers regarding the difficulty of folding the previous Hazchem Scale Cards.  We have therefore resdesigned the New Hazchem Scale Cards accordingly.

 

  

 

The Hazard Warning Panel

 

Emergency Action Codes (EAC)

The EAC provides information on:

• the fire extinguishing media to be used;
•  the level of PPE required;
• whether the spillage should be contained or may be diluted;
• whether there is a possibility of violent reaction;
• whether the substance poses a Public Safety Hazard.

1	COARSE SPRAY	3	FOAM
2	FINE SPRAY	4	DRY AGENT

P	V	LTS	DILUTE SPILLAGE
R
S	V	BA & FIRE KIT
T
W	V	LTS	CONTAIN SPILLAGE
X
Y	V	BA & FIRE KIT
Z

E	PUBLIC SAFETY HAZARD

K E Y	V		Can be violently or even explosively reactive
	LTS		Liquid tight chemical protective clothing used in combination with BA (Breathing Apparatus)
	DILUTE		Spillages may be washed to drains with large quantities of water. However due care must be taken to avoid unnecessary pollution of watercourses. For further information contact the Environment Agency or Scottish Environmental Protection Agency.
	CONTAIN		Prevent the spillage from entering drains and watercourses using any means available.
	DRY AGENT		Water MUST NOT be allowed to come into contact with the substance.
	E		People should be warned to stay indoors with all doors and windows closed but evacuation may need to be considered. Consult Control, Police and product expert.

  

Further Advice

More detailed advice on interpreting the EAC is given in 'Dangerous Goods Emergency Action Code List 2009' which you can buy as a book or download for free (ISBN 978 0 11 341326 3)

 

 

International Operations (ADR)

The ADR Hazard Identification Number (HIN, also known as the Kemler Code) is usually found in the UK on vehicles which are on international journeys. UK registered vehicles on domestic journeys should use the EAC. The HIN differs in its approach from the EAC, giving advice on the nature of the hazard presented by the goods as opposed to the actions to be taken when dealing with them.

 

 

 

 

Blank Plates

Orange plate without any numbers indicates vehicle carrying dangerous load (drums, packages, etc.) or multi-load tanker.

 

 

 

 

 

The Hazard Identification Number (HIN)

The hazard identification number consists of two or three figures. In general the figures indicate the following hazards:

2        Emission of gas due to pressure or to chemical reaction
3        Flammability of Liquids
4        Flammability of solid or seal-heating liquid
5        Oxidising (fire-intensifying) effect
6        Toxic or risk of infection
7        Radioactivity
8        Corrosivity
9         Risk of spontaneous violent reaction

 

NOTE:

Doubling of a figure indicates intensification of that particular hazard.

If the HIN is prefixed with an "X" this indicates the substance will react dangerously with water. For such substances, water may only be used by approval of experts.

Where the hazard associated with a substance can be adequately indicated by a single figure, this is followed by a zero.

 

The following combinations have special meanings - refer to Hazchem List or control:

22      Refrigerated liquefied gas, asphyxiant
323    Flammable liquid which reacts with water, emitting flammable gases
333    Pyrophoric liquid
362    Flammable liquid, toxic, which reacts with water, emitting flammable gases
382    Flammable liquid corrosive, which reacts with water, emitting flammable gases
423    Solid, flammable solid or self-heating solid which reacts with water, emitting flammable gases
432    Spontaneously flammable (pyrophoric) solid which reacts with water, emitting flammable gases
44      Flammable solid, in the molten state at an elevated temperature
446    Flammable solid, toxic, in the molten state at an elevated temperature
462    Toxic solid which reacts with water, emitting flammable gases
482    Corrosive solid which reacts with water, emitting flammable gases
539    Flammable organic peroxide
606    Infectious substance
623    Toxic liquid which reacts with water, emitting flammable gases
642    Toxic solid, which reacts with water, emitting flammable gases
823    Corrosive liquid which reacts with water, emitting flammable gases
842    Corrosive solid which reacts with water, emitting flammable gases
90      Environmentally hazardous substance; miscellaneous dangerous substance
99      Miscellaneous dangerous substance carried at an elevated temperature

 

 

Hazard Warning Diamonds

 

 

 

 

 

Supply Labelling

 

Supply labelling uses the same, or similar symbols to those seen on the Hazard warning diamonds used for transport labelling. However, as well as being a different shape and colour, different criteria are used to assign the risks. So, something classified as "Toxic" (Class 6.1) for transport may only be classified as "Harmful" for supply. Equally, something classed as "Toxic" (skull and cross-bones) for supply, such as a carcinogenic substance, may not be classified as hazardous for transport at all.

Equally, a particular substance may have different classifications for each system. Solvents may be classed as "Flammable" (Class 3) for transport, but "Harmful" or "Toxic" (equating to class 6.1) for supply. The reasons for this are the different types of risk exhibited in different situations. The end user, dealing with small quantities on a frequent basis over long time-periods, is at greater risk from any harmful/toxic effects due to contact with the product than from its flammable characteristics. The Emergency Services, however, will be dealing with a "one-off" situation which is not supposed to happen ever, involving several drums or tankerloads of the product, where the flammability hazard far outweighs the effects of contact with the product.

Classification can therefore be more intricate than it first appears; if you need any advice or guidance, see the Consultancy pages on this website.

 

 

NEW! GHS Labels

GHS is the internationally agreed Globally Harmonised System of Classification and Labelling of Chemicals. GHS aims to improve the health and safety of workers, consumers and the environment by ensuring consistent hazard communication on the chemicals being used.

In the EU, GHS has been implemented through the CLP Regulation (EC) No 1272/2008.

More information on GHS